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In the Hartree–Fock method of quantum mechanics, the Fock matrix is a matrix approximating the single-electron energy operator of a given quantum system in a given set of basis vectors.^{[1]}
It is most often formed in computational chemistry when attempting to solve the Roothaan equations for an atomic or molecular system. The Fock matrix is actually an approximation to the true Hamiltonian operator of the quantum system. It includes the effects of electron-electron repulsion only in an average way. Importantly, because the Fock operator is a one-electron operator, it does not include the electron correlation energy.
The Fock matrix is defined by the Fock operator. For the restricted case which assumes closed-shell orbitals and single-determinantal wavefunctions, the Fock operator for the i-th electron is given by:^{[2]}
where:
The Coulomb operator is multiplied by two since there are two electrons in each occupied orbital. The exchange operator is not multiplied by two since it has a non-zero result only for electrons which have the same spin as the i-th electron.
For systems with unpaired electrons there are many choices of Fock matrices.
Classical mechanics, Energy, Quantum field theory, Albert Einstein, Electromagnetism
Computational physics, Density functional theory, Computational chemistry, Schrödinger equation, Configuration interaction
Computer science, Chemistry, Quantum mechanics, Schrödinger equation, Machine learning
Slater determinant, Open shell, Hartree–Fock, Roothaan equations, Fock matrix
Post-Hartree–Fock, Hartree–Fock, Open shell, Molecular orbitals, Roothaan equations