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# Mole fraction

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 Title: Mole fraction Author: World Heritage Encyclopedia Language: English Subject: Collection: Publisher: World Heritage Encyclopedia Publication Date:

### Mole fraction

In chemistry, the mole fraction or molar fraction (x_i) is defined as the amount of a constituent (expressed in moles), n_i, divided by the total amount of all constituents in a mixture, n_{tot}:

x_i = \frac{n_i}{n_{tot}}

The sum of all the mole fractions is equal to 1:

\sum_{i=1}^{N} n_i = n_{tot} ; \; \sum_{i=1}^{N} x_i = 1

The same concept expressed with a denominator of 100 is the mole percent or molar percentage (mol%).

The mole fraction is also called the amount fraction. It is identical to the number fraction, which is defined as the number of molecules of a constituent N_i divided by the total number of all molecules N_{tot}. The mole fraction is sometimes denoted by the lowercase Greek letter \chi (chi) instead of a Roman x. For mixtures of gases, IUPAC recommends the letter y.

The National Institute of Standards and Technology of the United States prefers the term amount-of-substance fraction over mole fraction because it does not contain the name of the unit mole.

Whereas mole fraction is a ratio of moles to moles, molar concentration is a ratio of moles to volume.

The mole fraction is one way of expressing the composition of a mixture with a dimensionless quantity; mass fraction (percentage by weight, wt%) and volume fraction (percentage by volume, vol%) are others.

## Contents

• Properties 1
• Related quantities 2
• Mass fraction 2.1
• Mole percentage 2.2
• Mass concentration 2.3
• Molar concentration 2.4
• Mass and molar mass 2.5
• Spatial variation and gradient 3
• References 4

## Properties

Mole fraction is used very frequently in the construction of phase diagrams. It has a number of advantages:

• it is not temperature dependent (such as molar concentration) and does not require knowledge of the densities of the phase(s) involved
• a mixture of known mole fraction can be prepared by weighing off the appropriate masses of the constituents
• the measure is symmetric: in the mole fractions x=0.1 and x=0.9, the roles of 'solvent' and 'solute' are reversed.
• In a mixture of ideal gases, the mole fraction can be expressed as the ratio of partial pressure to total pressure of the mixture

## Related quantities

### Mass fraction

The mass fraction w_i can be calculated using the formula

w_i = x_i \cdot \frac {M_i}{M}

where M_i is the molar mass of the component i and M is the average molar mass of the mixture.

Replacing the expression of the molar mass:

w_i = x_i \cdot \frac {M_i}{\sum_i x_i M_i}

### Mole percentage

Multiplying mole fraction by 100 gives the mole percentage, also referred as amount/amount percent (abbreviated as n/n%).

### Mass concentration

The conversion to and from mass concentration \rho_i is given by:

x_i = \frac{\rho_i}{\rho} \cdot \frac{M}{M_i}

where M is the average molar mass of the mixture.

\rho_i = x_i \rho \cdot \frac{M_i}{M}

### Molar concentration

The conversion to molar concentration c_i is given by:

c_i = \frac = x_i c

or

c_i = \frac

where M is the average molar mass of the solution, c total molar concentration and \rho is the density of the solution .

### Mass and molar mass

The mole fraction can be calculated from the masses m_i and molar masses M_i of the components:

x_i= \frac}}}}