Restricted openshell Hartree–Fock (ROHF) is a variant of Hartree–Fock theory for open shell molecules. It uses doubly occupied molecular orbitals as far as possible and then singly occupied orbitals for the unpaired electrons. This is the simple picture for open shell molecules but it is difficult to implement. The foundations of the ROHF method were first formulated by Roothaan in a celebrated paper ^{[1]} and then extended by various authors, see e.g.^{[2]}^{[3]}^{[4]} for indepth discussions.
As with restricted Hartree–Fock theory for closed shell molecules, it leads to Roothaan equations written in the form of a generalized eigenvalue problem

\mathbf{F} \mathbf{C} = \mathbf{S} \mathbf{C} \mathbf{\epsilon}
Where F is the socalled Fock matrix (which is a function of C), C is a matrix of coefficients, S is the overlap matrix of the basis functions, and \epsilon is the (diagonal, by convention) matrix of orbital energies. Unlike restricted Hartree–Fock theory for closed shell molecules, the form of the Fock matrix is not unique. Different socalled canonicalisations can be used leading to different orbitals and different orbital energies, but the same total wavefunction, total energy, and other observables.
In contrast to unrestricted Hartree–Fock (UHF), the ROHF wave function is a satisfactory eigenfunction of the total spin operator  \mathbf{S}^2 (i.e. no Spin contamination).
Developing postHartree–Fock methods based on a ROHF wave function is inherently more difficult than using a UHF wave function, due to the lack of a unique set of molecular orbitals.^{[5]} However, different choices of reference orbitals have shown to provide similar results,^{[6]} and thus many different postHartree–Fock methods have been implemented in a variety of electronic structure packages. Many (but not all) of these postHartree–Fock methods are completely invariant with respect to orbital choice (assuming that no orbitals are "frozen" and thus not correlated).^{[7]} The ZAPT2 version of Møller–Plesset perturbation theory specifies the choice of orbitals.
References

^ Roothaan, C. C. J. (1960). "Selfconsistent field theory for open shells of electronic systems". Rev. Mod. Phys. 32 (2): 179–185.

^ Carbó, R.; Riera, J. M. (1978). "Historical Review". A General SCF Theory. Lecture Notes in Chemistry 5. Springer. pp. 1–4.

^ McWeeny, R. (1992). Methods of Molecular Quantum Mechanics (2nd ed.). Academic Press.

^ Plakhutin, B. N. (2002). Sen, K. D., ed. Reviews of Modern Quantum Chemistry 1. Word Scientific. pp. 16–42.

^ Glaesemann, Kurt R.; Schmidt, Michael W. (2010). "On the Ordering of Orbital Energies in HighSpin ROHF†". The Journal of Physical Chemistry A 114 (33): 8772–8777.

^ Jensen, F. (2007). Introduction to Computational Chemistry (2nd ed.). Wiley.

^ Crawford, T. Daniel; Schaefer, Henry F.; Lee, Timothy J. (1996). "On the energy invariance of openshell perturbation theory with respect to unitary transformations of molecular orbitals". The Journal of Chemical Physics 105 (3): 1060.
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